1075-49-6
- Product Name：4-Vinylbenzoic acid
- Molecular Formula：C9H8O2
- Purity：99%
- Molecular Weight：148.161
Product Details
pd_meltingpoint:142-144 °C(lit.)
Appearance:Off-white solid
Purity:99%
Reputable manufacturer supply 4-Vinylbenzoic acid 1075-49-6 in stock with high standard
- Molecular Formula:C9H8O2
- Molecular Weight:148.161
- Appearance/Colour:Off-white solid
- Vapor Pressure:0.000901mmHg at 25°C
- Melting Point:142-144 °C(lit.)
- Refractive Index:1.5290 (estimate)
- Boiling Point:291.3 °C at 760 mmHg
- PKA:4.24±0.10(Predicted)
- Flash Point:132.8 °C
- PSA：37.30000
- Density:1.158 g/cm3
- LogP:2.02780
4-Vinylbenzoic acid(Cas 1075-49-6) Usage
InChI:InChI=1/C9H8O2/c1-2-7-3-5-8(6-4-7)9(10)11/h2-6H,1H2,(H,10,11)/p-1
1075-49-6 Relevant articles
Structural insights into the role of the acid-alcohol pair of residues required for dioxygen activation in cytochrome P450 enzymes
Coleman, Tom,Stok, Jeanette E.,Podgorski, Matthew N.,Bruning, John B.,De Voss, James J.,Bell, Stephen G.
, p. 583 - 596 (2020)
The cytochrome P450 heme monooxygenases ...
High density scaffolding of functional polymer brushes: Surface initiated atom transfer radical polymerization of active esters
Orski, Sara V.,Fries, Kristen H.,Sheppard, Gareth R.,Locklin, Jason
, p. 2136 - 2143 (2010)
In this Article, we describe a method, f...
Precision polyelectrolytes
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, p. 1517 - 1519 (2012)
Charged macromolecules with controlled m...
Preparation and Characterization of Some Nickel(II) Tetra-aza Macrocyclic Complexes bearing Pendant Polymerisable Groups as Part of the Ligand Superstructure
Cameron, James H.,Graham, Stephen
, p. 1599 - 1608 (1989)
The synthesis and characterisation of so...
Amphiphilic polymethacrylate- and polystyrene-based chemical delivery systems for damascones
Berthier, Damien,Trachsel, Alain,Fehr, Charles,Ouali, Lahoussine,Herrmann, Andreas
, p. 3089 - 3108 (2005)
Amphiphilic polystyrene- and polymethacr...
Selective Transfer Semihydrogenation of Alkynes with H2O (D2O) as the H (D) Source over a Pd-P Cathode
Liu, Cuibo,Lu, Siyu,Wang, Changhong,Wu, Yongmeng,Zhang, Bin
supporting information, p. 21170 - 21175 (2020/09/11)
We reported a selective semihydrogenatio...
Cobalt-Catalyzed Reductive Carboxylation of Aryl Bromides with Carbon Dioxide
Hang, Wei,Yi, Yaping,Xi, Chanjuan
supporting information, p. 2337 - 2341 (2020/04/30)
Cobalt-catalyzed reductive carboxylation...
Manganese-Catalyzed N-Alkylation of Sulfonamides Using Alcohols
Reed-Berendt, Benjamin G.,Morrill, Louis C.
, p. 3715 - 3724 (2019/03/30)
An efficient manganese-catalyzed N-alkyl...
1075-49-6 Process route
-
-
105-06-6
1,4-Divinylbenzene
-
-
100-21-0
terephthalic acid
-
-
1075-49-6
4-ethenylbenzoic acid
-
-
1791-26-0
4-vinyl-benzaldehyde
-
-
623-27-8
terephthalaldehyde,
| Conditions | Yield |
|---|---|
|
With
pyridine; dimethylsulfide; oxygen; ozone;
Yield given. Multistep reaction;
1.) CH2Cl2, -78 deg C- -75 deg C, 5 hrs., 2.) CH2Cl2, r.t., 2 hrs.;
|
-
-
124-38-9,18923-20-1
carbon dioxide
-
-
676593-23-0
5,5-dimethyl-2-(4-ethenylphenyl)-1,3,2-dioxaborinane
-
-
1075-49-6
4-ethenylbenzoic acid
| Conditions | Yield |
|---|---|
|
With
potassium tert-butylate; copper(l) chloride; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride;
In
tetrahydrofuran;
at 70 ℃;
for 24h;
under 760.051 Torr;
|
93% |
|
With
(1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide; potassium tert-butylate;
In
tetrahydrofuran;
for 24h;
under 760.051 Torr;
Inert atmosphere;
Schlenk technique;
Reflux;
Green chemistry;
|
88% |
|
carbon dioxide; 5,5-dimethyl-2-(4-ethenylphenyl)-1,3,2-dioxaborinane;
With
potassium tert-butylate; silver(I) acetate; triphenylphosphine;
In
tetrahydrofuran;
at 70 ℃;
for 16h;
under 15201 Torr;
Inert atmosphere;
Autoclave;
With
hydrogenchloride;
In
tetrahydrofuran; water;
Inert atmosphere;
|
82% |
|
carbon dioxide; 5,5-dimethyl-2-(4-ethenylphenyl)-1,3,2-dioxaborinane;
With
copper(l) iodide; 5,5-bis(4,5-dihydrooxazol-2-yl)nonane; cesium fluoride;
In
N,N-dimethyl-formamide;
at 90 ℃;
for 10h;
under 760.051 Torr;
With
hydrogenchloride; water;
In
N,N-dimethyl-formamide;
|
70% |
1075-49-6 Upstream products
-
3435-51-6
4-ethenylbenzonitrile
-
1076-96-6
methyl 4-vinylbenzoate
-
1791-26-0
4-vinyl-benzaldehyde
-
1073-67-2
4-vinylbenzyl chloride
1075-49-6 Downstream products
-
1076-96-6
methyl 4-vinylbenzoate
-
3661-73-2
4-carbamoylstyrene
-
10537-63-0
1-(4-vinylphenyl)ethanone
-
85828-48-4
diethyl p-vinylbenzoyl-L-glutamate
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