503-30-0
- Product Name:Trimethylene oxide
- Molecular Formula:C3H6O
- Purity:99%
- Molecular Weight:58.08
Product Details
pd_meltingpoint:-97 °C
Appearance:Clear, colorless liquid
Purity:99%
Factory supply Trimethylene oxide 503-30-0 with low price
- Molecular Formula:C3H6O
- Molecular Weight:58.08
- Appearance/Colour:Clear, colorless liquid
- Vapor Pressure:5.09 psi ( 20 °C)
- Melting Point:-97 °C
- Refractive Index:n20/D 1.392(lit.)
- Boiling Point:49 °C at 760 mmHg
- Flash Point:−19 °F
- PSA:9.23000
- Density:0.936 g/cm3
- LogP:0.40670
Trimethylene oxide(Cas 503-30-0) Usage
|
Air & Water Reactions |
Highly flammable. Water soluble. |
|
Reactivity Profile |
TRIMETHYLENE OXIDE reacts with Grignard reagents and organolithium compounds. TRIMETHYLENE OXIDE is also incompatible with oxidizing agents and strong acids. . An explosion occurred when propylene oxide was added to epoxy resin. Polymerization was catalyzed by amine accelerator in the resin [Bretherick 1995]. Propylene oxide and sodium hydroxide base-catalyzed the polymerization of the former, causing ignition and explosion of a drum of the crude product. [Combust Sci. Technol., 1983]. |
|
Fire Hazard |
TRIMETHYLENE OXIDE is flammable. |
|
Safety Profile |
Moderately toxic by subcutaneous route. May be narcotic in high concentrations. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes |
|
Purification Methods |
Distil oxetane twice from sodium metal and then fractionate it through a small column at atmospheric pressure, b 47.0-47.2o. It can also be purified by preparative gas chromatography using a 2m silica gel column. Alternatively, add KOH pellets (50g for 100g of oxetane) and distil it through an efficient column or a column packed with 1/4in Berl Saddles with the main portion boiling at 45-50o being collected and redistilled over fused KOH. [Noller Org Synth Coll Vol III 835 1955, Dittmer et al. J Am Chem Soc 79 4431 1957, Beilstein 17 H 6, 17 I 3, 17 II 12, 17 III/IV 13, 17/1 V 11.] |
|
Definition |
ChEBI: A saturated organic heteromonocyclic parent that is a four-membered ring comprising of three carbon atoms and an oxygen atom. |
|
General Description |
Clear, colorless liquid with an agreeable aromatic odor. |
InChI:InChI=1/C3H6O/c1-2-4-3-1/h1-3H2
503-30-0 Relevant articles
RADICAL CATIONS OF VARIOUS ETHENE, ETHINE AND CYCLIC ETHERS
Symons, Martyn C. R.,Wren, Brendon W.
, p. 2315 - 2318 (1983)
We have prepared the cations .(1+), .(1+...
Photochemical reactions of trimethylene oxide radical cations in Freon matrices at 77 K
Mel'nikov, Mikhail Ya.,Belevskii, Vladilen N.,Kalugina, Anastasiya D.,Mel'nikova, Ol'ga L.,Pergushov, Vladimir I.,Tyurin, Daniil A.
, p. 305 - 306 (2008)
Radical cations of trimethylene oxide un...
-
Allen,Hibbert
, p. 1398,1399 (1934)
-
Study of the low temperature oxidation of propane
Cord, Maximilien,Husson, Benoit,Lizardo Huerta, Juan Carlos,Herbinet, Olivier,Glaude, Pierre-Alexandre,Fournet, Rene,Sirjean, Baptiste,Battin-Leclerc, Frederique,Ruiz-Lopez, Manuel,Wang, Zhandong,Xie, Mingfeng,Cheng, Zhanjun,Qi, Fei
, p. 12214 - 12228 (2013/02/25)
The low-temperature oxidation of propane...
Method for the preparation of 1-deoxy baccatin III, 1-deoxy taxol and 1-deoxy taxol analogs
-
, (2008/06/13)
1-Deoxybaccatin III, 1-deoxytaxol and 1-...
Process for production of an oxetane
-
, (2008/06/13)
A process for production of an oxetane, ...
503-30-0 Process route
-
-
287-25-2
(S)-propyleneoxide
-
-
503-30-0
trimethylene oxide
| Conditions | Yield |
|---|---|
|
With
hydrogen;
palladium on activated charcoal;
at 0 ℃;
|
-
-
628-09-1
3-Chloropropyl acetate
-
-
503-30-0
trimethylene oxide
| Conditions | Yield |
|---|---|
|
With
potassium hydroxide;
In
water;
Heating;
|
40% |
|
With
potassium hydroxide; water;
at 150 ℃;
|
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104-58-5
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