13965-03-2
- Product Name：Bis(triphenylphosphine)palladium(II) chloride
- Molecular Formula：C36H30Cl2P2Pd
- Purity：99%
- Molecular Weight：701.908
Product Details
pd_meltingpoint:260 °C
Appearance:Yellow crystalline powder
Purity:99%
Chinese factory supply Bis(triphenylphosphine)palladium(II) chloride 13965-03-2 in stock with high standard
- Molecular Formula:C36H30Cl2P2Pd
- Molecular Weight:701.908
- Appearance/Colour:Yellow crystalline powder
- Vapor Pressure:0Pa at 25℃
- Melting Point:260 °C
- Boiling Point:360 °C at 760 mmHg
- Flash Point:181.7 °C
- PSA：27.18000
- LogP:8.26860
Bis(triphenylphosphine)palladium(II) chloride(Cas 13965-03-2) Usage
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Synthesis |
Bis(triphenylphosphine)palladium(II) chloride may be synthesized by treating palladium(II) chloride with triphenylphosphine:PdCl2 + 2 PPh3 → PdCl2(PPh3)2 |
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Reactions |
Precatalyst for the carbonylative cyclization of malonate derivatives.Catalyst used in the double allylation of activated olefins.Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans.Precatalyst for the homocoupling of terminal alkynes.Precatalyst in the cross-coupling of alkynylsilanols and aryl halides.Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles.Catalyst for a tandem Heck reaction/C-H functionalization.Catalyst for direct arylation of tautomerizable heterocycles. |
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Flammability and Explosibility |
Nonflammable |
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General Description |
Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium. |
InChI:InChI=1/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2
13965-03-2 Relevant articles
ELECTROCHEMICAL BEHAVIOUR OF Pd(0) AND Pd(II) COMPLEXES WITH TRIPHENYLPHOSPHINE IN DIMETHYLFORMAMIDE.
Vasini, E. J.,Giordano, M. C.
, p. 205 - 212 (1988)
The electrochemical behaviour of a palla...
Influences of the electronic and steric effects of the substituents in cyclopalladation of ferrocenylhydrazones
Lopez, Conception,Granell, Jaume
, p. 211 - 225 (1998)
The syntheses and characterization of se...
Metal coordination mediated reversible conversion between linear and cross-linked supramolecular polymers
Wang, Feng,Zhang, Jinqiang,Ding, Xia,Dong, Shengyi,Liu, Ming,Zheng, Bo,Li, Shijun,Wu, Ling,Yu, Yihua,Gibson, Harry W.,Huang, Feihe
, p. 1090 - 1094 (2010)
(Figure Presented) The dynamic duo: Diff...
Regioselectivity in the Sonogashira coupling of 4,6-dichloro-2-pyrone
Fairlamb, Ian J. S.,O'Brien, Ciara T.,Lin, Zhenyang,Lam, King Chung
, p. 1213 - 1216 (2006)
The Sonogashira cross-coupling of 4,6-di...
Dinuclear PdII/PtIIcomplexes [M2(phosphine)n(thio-ligand)3]Cl incorporating N,S-bridged pyridine-2-thiolate and benzimidazoline-2-thiolate
Lobana, Tarlok S.,Sandhu, Amanpreet K.,Mahajan, Rakesh K.,Hundal, Geeta,Gupta, Sushil K.,Butcher, Ray J.,Castineiras, Alfonso
, p. 25 - 35 (2017)
Equimolar reaction of [PdCl2(dppm)] {dpp...
Quasi-homogeneous catalytic conversion of CO2into quinazolinones inside a metal-organic framework microreactor
Cheng, Peng,Gao, Jianbo,Ma, Jian-Gong,Zhou, Zhenzhen
, p. 5456 - 5460 (2021)
Management of CO2 has been attracting gr...
Schiff base triphenylphosphine palladium (II) complexes: Synthesis, structural elucidation, electrochemical and biological evaluation
Shabbir, Muhammad,Akhter, Zareen,Ahmad, Iqbal,Ahmed, Safeer,Shafiq, Maryam,Mirza, Bushra,McKee, Vickie,Munawar, Khurram Shahzad,Ashraf, Ahmad Raza
, p. 250 - 258 (2016)
The complexes N-(2-oxidophenyl)salicylid...
Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)
de León, Antonio,Pons, Josefina,García-Antón, Jordi,Solans, Xavier,Font-Bardía, Mercè,Ros, Josep
, p. 3801 - 3806 (2009)
Complex [PdCl(bdtp)](BF4), in presence o...
Interaction of palladium(II) complexes with amino-alcohols: Synthesis of new amino-carbonyl complexes, key intermediates to cyclic carbamates
Giannoccaro, Potenzo,Dibenedetto, Angela,Gargano, Michele,Quaranta, Eugenio,Aresta, Michele
, p. 967 - 975 (2008)
The interaction between carbon monoxide ...
Palladium catalyzed hydrodechlorination of α-chloroacetophenones by hydrogen transfer from the H2O-CO system
Cavinato,Pasqualetto,Ronchin,Toniolo
, p. 15 - 22 (1997)
PdCl2(PPh3)2, in combination with an ext...
Catalytic carbonylation of 4-penten-1-ol to ε-caprolactone and oligocaprolactone
Funk, Jeffrey K.,Newsham, David K.,Goldstein, David N.,Liu, Shengsheng,Sen, Ayusman
, p. 185 - 192 (2005)
A catalyst consisting of Pd2(dba)3 + 2 X...
UNUSUAL REARRANGEMENT OF ?-VINYLPALLADIUM COMPLEXES INTO η2-OLEFIN COMPLEXES. THE STRUCTURE OF (η2-1-TRIPHENYLPHOSPHONIUM-2-CARBOMETHOXYETHYLENE)-(TRIPHENYLPHOSPHINE)IODOPALLADATE
Rybin, L. V.,Petrovskaya, E. A.,Rubinskaya, M. I.,Kuz'mina, L. G.,Struchkov, Yu.T.,et al.
, p. 119 - 130 (1985)
β-Substituted ?-vinylpalladium complexes...
Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation
Qin, Guiping,Li, Lixin,Li, Jiawen,Huang, Hanmin
, p. 12490 - 12493 (2015)
A new strategy for selective insertion o...
Convergent synthesis of alkynylbis(bidentate phosphine)ruthenium dendrimers
McDonagh, Andrew M.,Powell, Clem E.,Morrall, Joseph P.,Cifuentes, Marie P.,Humphrey, Mark G.
, p. 1402 - 1413 (2003)
The convergent synthesis of alkynylbis(b...
Fluoride-assisted reduction of palladium(II) phosphine complexes
Mason, Mark R.,Verkade, John G.
, p. 864 - 865 (1990)
PdCl2 in the presence of chelating or mo...
REDOX TROPONIZATION OF 4-METHYL-4-DIBROMOMETHYL-2,5-CYCLOHEXADIEN-1-ONE BY HTE ACTION OF Pd(PPh3)4
Nikanorov, V. A.,Gavrilova, G. V.,Rozenberg, V. I.,Reutov, O. A.
, (1987)
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Thermodynamically stable, highly emissive poly(diphenylacetylene) derivative containing long alkyl side chain without silylene linkage
Jin, Young-Jae,Kawamura, Yuto,Teraguchi, Masahiro,Aoki, Toshiki,Kwak, Giseop
, p. 81 - 86 (2017)
A PDPA derivative with a long alkyl side...
Charge-Assisted phosph(v)azane anion receptors
Bond, Andrew D.,Goodman, Jonathan M.,Lee, Sanha,Plajer, Alex J.,Wright, Dominic S.
, p. 3403 - 3407 (2020)
Coordination of Cu(i) or Pd(ii) to selen...
Erratum: Oxidative addition of Sn-C bonds on palladium(0): Identification of palladium-stannyl species and a facile synthetic route to diphosphinostannylene-palladium complexes (Organometallics (2010) 29:22 5904-5911. DOI: 10.1021/om1007067)
Derrah, Eric J.,Warsink, Stefan,De Pater, Jeroen J. M.,Cabon, Yves,Reboule, Irena,Lutz, Martin,Klein Gebbink, Robertus J. M.,Deelman, Berth-Jan
, p. 2914 - 2918 (2014)
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Mixed ligand cobalt and palladium complexes containing triphenylphosphine and a hydrazone: Synthesis and application in non-linear optics
Ramakrishna, Dileep
, p. 462 - 466 (2021)
Mixed ligand complexes of cobalt and pal...
Synthesis of a diferrocenylvinylidene complex by migration of a ferrocenyl substituent
Korb, Marcus,Moggach, Stephen A.,Low, Paul J.
supporting information, p. 4251 - 4254 (2021/05/05)
An unusual 1,2-ferrocenyl migration has ...
Rip It off: Nitro to Nitroso Reduction by Iron Half-Sandwich Complexes
Korb, Marcus,Hosseini Ghazvini, Seyed Mohammad Bagher,Moggach, Stephen A.,Meunier, Jean-Fran?ois,Bousseksou, Azzedine,Low, Paul J.
supporting information, p. 4986 - 4995 (2021/04/06)
Activation of [FeCl(dppe)Cp] (1) by chlo...
Epoxyanthracene Derivatives and Dicarbonylation on Benzene Ring via Hexadehydro-Diels-Alder (HDDA) Derived Benzynes with Oxazoles
Hu, Qiong,Hu, Yimin,Lei, Yu,Yang, Feihu,Zheng, Xiaojie,Zhu, Wenjing
supporting information, (2021/11/22)
A capture reaction of hexadehydro-Diels-...
13965-03-2 Process route
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1112-67-0
tetrabutyl-ammonium chloride
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C52H68N4P4PdSe2(2+)*2BF4(1-)*CH2Cl2
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13965-03-2
bis-triphenylphosphine-palladium(II) chloride
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429-42-5
tetrabutylammonium tetrafluoroborate
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C16H38N4P2Se2
| Conditions | Yield |
|---|---|
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In
chloroform-d1;
|
-
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14221-01-3
tetrakis(triphenylphosphine) palladium(0)
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993-16-8
methyltin(IV) trichloride
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28966-81-6
trans-bis(triphenylphosphine)palladium dichloride
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-
15604-37-2,13965-03-2,28966-81-6
bis(triphenylphosphine)palladium(II) chloride
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cis-[PdCl(SnCl2Me)(PPh3)2]
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trans-[PdCl(SnCl2Me)(PPh3)2]
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603-35-0
triphenylphosphine
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-
tin(ll) chloride
| Conditions | Yield |
|---|---|
|
In
tetrahydrofuran-d8;
Inert atmosphere;
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13965-03-2 Upstream products
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603-35-0
triphenylphosphine
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114129-99-6
trans-[Pd(triphenylphosphine)2(N4CPh)2]
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98-88-4
benzoyl chloride
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14349-67-8
tetrachloropalladium anion
13965-03-2 Downstream products
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265114-75-8
bis(1,2-bis(diphenylphosphinoethynyl)benzene)palladium(0)
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151665-70-2
(E)-3,5-diphenylpent-2-en-4-ynoic acid methyl ester
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186773-03-5
N-(tert-butoxycarbonyl)4-(2-thiazolyl)-L-phenylalanine methyl ester
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726138-31-4
2-amino-3,5-diphenyl-pyridine
Relevant Products
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1-BromooctaneCAS：111-83-1
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1,6-dibromopyreneCAS：27973-29-1
