42523-29-5

  • Product Name:2,7-Dihydroxy-9-fluorenone
  • Molecular Formula:C13H8O3
  • Purity:99%
  • Molecular Weight:212.205
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Product Details

pd_meltingpoint:338 °C

Appearance:Brown red powder

Purity:99%

Cost-effective and customizable 2,7-Dihydroxy-9-fluorenone 42523-29-5 supplier

  • Molecular Formula:C13H8O3
  • Molecular Weight:212.205
  • Appearance/Colour:Brown red powder 
  • Vapor Pressure:1.63E-08mmHg at 25°C 
  • Melting Point:338 °C 
  • Refractive Index:1.749 
  • Boiling Point:444.5 °C at 760 mmHg 
  • PKA:8.87±0.20(Predicted) 
  • Flash Point:236.7 °C 
  • PSA:57.53000 
  • Density:1.497 g/cm3 
  • LogP:2.30920 

2,7-Dihydroxy-9-fluorenone(Cas 42523-29-5) Usage

InChI:InChI=1/C13H8O3/c14-7-1-3-9-10-4-2-8(15)6-12(10)13(16)11(9)5-7/h1-6,14-15H

42523-29-5 Relevant articles

Photodecaging from 9-substituted 2,7-dihydroxy and dimethoxyfluorenes: Competition between heterolytic and homolytic pathways

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, p. 920 - 930 (2011)

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, p. 248 - 250 (2004)

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Synthesis of Fluorenones from Benzaldehydes and Aryl Iodides: Dual C-H Functionalizations Using a Transient Directing Group

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supporting information, p. 1140 - 1143 (2017/03/14)

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42523-29-5 Process route

4,4'-dihydroxy-biphenyl-2-carboxylic acid methyl ester
765944-63-6

4,4'-dihydroxy-biphenyl-2-carboxylic acid methyl ester

2,7-dihydroxy-9H-fluoren-9-one
42523-29-5

2,7-dihydroxy-9H-fluoren-9-one

Conditions
Conditions Yield
With zinc(II) chloride; at 110 - 120 ℃; for 2h;
95%
Multi-step reaction with 2 steps
1: sodium hydroxide / ethanol / 78 °C
2: thionyl chloride / 79 °C
With sodium hydroxide; thionyl chloride; In ethanol; 2: Friedel-Crafts acylation;
4-bromo-3-iodo-phenol
202865-84-7

4-bromo-3-iodo-phenol

meta-hydroxybenzaldehyde
100-83-4

meta-hydroxybenzaldehyde

2,7-dihydroxy-9H-fluoren-9-one
42523-29-5

2,7-dihydroxy-9H-fluoren-9-one

Conditions
Conditions Yield
With palladium diacetate; potassium hydrogencarbonate; DL-Pro-NHMe; In tert-Amyl alcohol; at 120 ℃; for 24h; Inert atmosphere;
74%

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