84563-54-2
- Product Name：Bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate
- Molecular Formula：C21H26F3IO3S
- Purity：99%
- Molecular Weight：542.401
Product Details
pd_meltingpoint:237 °C(lit.)
Purity:99%
Quality Factory Hot Selling Bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate 84563-54-2 with Fast Shipping
- Molecular Formula:C21H26F3IO3S
- Molecular Weight:542.401
- Melting Point:237 °C(lit.)
- PSA：65.58000
- LogP:3.54220
BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLATE(Cas 84563-54-2) Usage
InChI:InChI=1/C20H26I.CHF3O3S/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6;2-1(3,4)8(5,6)7/h7-14H,1-6H3;(H,5,6,7)/q+1;/p-1
84563-54-2 Relevant articles
Transition Metal-Free N-Arylation of Amino Acid Esters with Diaryliodonium Salts
Kervefors, Gabriella,Kersting, Leonard,Olofsson, Berit
supporting information, p. 5790 - 5795 (2021/03/08)
A transition metal-free approach for the...
N1- and N3-Arylations of Hydantoins Employing Diaryliodonium Salts via Copper(I) Catalysis at Room Temperature
Abha Saikia, Raktim,Barman, Dhiraj,Dutta, Anurag,Jyoti Thakur, Ashim
supporting information, p. 400 - 410 (2020/12/17)
Copper(I)-catalyzed N-arylation (both N1...
Direct Copper-Catalyzed C-3 Arylation of Diphenylphosphine Oxide Indoles
Huang, Xiao-Ling,Li, Chong,Wang, Juan,Yang, Shang-Dong
supporting information, (2021/10/25)
We have developed a simple and effective...
Spatial anion control on palladium for mild C-H arylation of arenes
Dhankhar, Jyoti,González-Fernández, Elisa,Dong, Chao-Chen,Mukhopadhyay, Tufan K.,Linden, Anthony,?ori?, Ilija
supporting information, p. 19040 - 19046 (2020/11/13)
C-H arylation of arenes without the use ...
84563-54-2 Process route
-
-
253185-03-4,253185-04-5
tert-butylbenzene
-
-
1493-13-6
trifluorormethanesulfonic acid
-
-
35779-04-5
1-tert-butyl-4-iodobenzene
-
-
84563-54-2
bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate
| Conditions | Yield |
|---|---|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 1h;
Inert atmosphere;
Schlenk technique;
Sealed tube;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
|
|
|
With
m-chloroperoxybenzoic acid;
In
dichloromethane;
at 0 ℃;
Sealed tube;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at -78 ℃;
for 3h;
Temperature;
Solvent;
Sealed tube;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 - 20 ℃;
for 3.16667h;
|
-
-
253185-03-4,253185-04-5
tert-butylbenzene
-
-
1493-13-6
trifluorormethanesulfonic acid
-
-
84563-54-2
bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate
| Conditions | Yield |
|---|---|
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 0.166667h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 - 20 ℃;
for 0.416667h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 0.166667h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 0.166667h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 0.333333h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 0.333333h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 0.333333h;
Sealed tube;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 - 20 ℃;
for 0.333333h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 0.333333h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 1h;
|
78% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 1h;
Inert atmosphere;
Sealed tube;
|
77% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
1,2-dichloro-ethane;
at 20 ℃;
for 0.0166667h;
Inert atmosphere;
Flow reactor;
Sonication;
|
70% |
|
tert-butylbenzene;
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 ℃;
for 0.5h;
Reflux;
trifluorormethanesulfonic acid;
In
dichloromethane;
at 20 ℃;
for 6h;
|
64.5% |
|
tert-butylbenzene;
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 ℃;
for 0.0833333h;
trifluorormethanesulfonic acid;
at 0 - 20 ℃;
for 2.08333h;
|
57% |
|
tert-butylbenzene;
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 ℃;
for 0.166667h;
trifluorormethanesulfonic acid;
In
dichloromethane;
at 0 ℃;
|
50% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 - 20 ℃;
for 2h;
|
43% |
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
|
|
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane; water;
at 0 - 20 ℃;
for 0.333333h;
Schlenk technique;
Inert atmosphere;
|
|
|
With
iodine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
Inert atmosphere;
|
84563-54-2 Upstream products
-
253185-03-4
tert-butylbenzene
-
1493-13-6
trifluorormethanesulfonic acid
-
358-23-6
trifluoromethylsulfonic anhydride
-
35779-04-5
1-tert-butyl-4-iodobenzene
84563-54-2 Downstream products
-
1151782-18-1
(E)-1-(tert-butyl)-4-(3,3-dimethylbut-1-en-1-yl)benzene
-
1374007-21-2
N-(4-(tert-butyl)phenyl)-S,S-dimethylsulfoximine
-
1374007-20-1
N-(4-(tert-butyl)phenyl)-S-methyl-S-(4-methylphenyl)-sulfoximine
-
1392826-96-8
(E)-3-(4-tert-butylphenyl)-2-propen-1-ol acetate
Relevant Products
-
Diphenyliodonium trifluoromethanesulfonateCAS：66003-76-7
-
4-(N,N-Diphenylamino)benzaldehydeCAS：4181-05-9
-
Bis(4-iodophenyl)iodonium Trifluoromethanesulfonate
CAS：647843-90-1
