110-53-2
- Product Name：1-Bromopentane
- Molecular Formula：C5H11Br
- Purity：99%
- Molecular Weight：151.046
Product Details
pd_meltingpoint:- 95 °C(lit.)
Appearance:Colorless liquid
Purity:99%
Top Quality 1-Bromopentane 110-53-2 Hot Sell In Stock
- Molecular Formula:C5H11Br
- Molecular Weight:151.046
- Appearance/Colour:Colorless liquid
- Vapor Pressure:12.5mmHg at 25°C
- Melting Point:- 95 °C(lit.)
- Refractive Index:n20/D 1.444(lit.)
- Boiling Point:129.3 °C at 760 mmHg
- Flash Point:31.1 °C
- PSA：0.00000
- Density:1.215 g/cm3
- LogP:2.57150
1-Bromopentane(Cas 110-53-2) Usage
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 86, p. 5037, 1964 DOI: 10.1021/ja01076a084 |
|
General Description |
1-Bromopentane undergoes phase transfer catalysed alkylation reaction with 2′-hydroxy acetophenone using tetrabutyl ammonium bromide as catalyst. |
|
Safety Profile |
Moderately toxic byintraperitoneal route. Slightly toxic by inhalation. Whenheated to decomposition it emits toxic vapors of Br-. |
|
Purification Methods |
Wash the bromide with conc H2SO4, then water, 10% Na2CO3 solution, again with water, dry with CaCl2 or K2CO3, and fractionally distil it just before use. [Beilstein 1 IV 312.] |
InChI:InChI=1/C5H11Br/c1-2-3-4-5-6/h2-5H2,1H3
110-53-2 Relevant articles
-
Kharasch et al.
, p. 1659 (1952)
-
-
Williams,Hamill
, p. 1857 (1950)
-
Silica Supported Acids (HClO4-SiO2, KHSO4-SiO2) as Eco-friendly Reusable Catalysts for Bromodecarboxylation of α,β-Unsaturated Carboxylic Acids using KBr under Solvothermal and Solvent-Free Conditions
Arisha, Samba Shiva Rao,Gugulothu, Yaku,Kamatala, Chinna Rajanna,Nagannagari, Maasi Reddy,Pulusu, Vijay Shekar,Utkoor, Umesh Kumar,Yelike, Hemanth Sriram
, p. 535 - 542 (2022/02/22)
A mild procedure has been developed for ...
Rethinking Basic Concepts-Hydrogenation of Alkenes Catalyzed by Bench-Stable Alkyl Mn(I) Complexes
Weber, Stefan,St?ger, Berthold,Veiros, Luis F.,Kirchner, Karl
, p. 9715 - 9720 (2019/10/14)
An efficient additive-free manganese-cat...
Facile continuous process for gas phase halogen exchange over supported alkyl phosphonium salts
Sharma, Priti,Sasson, Yoel
, p. 2824 - 2828 (2018/02/06)
Chloride-bromide halogen exchange was re...
An efficient conversion of alcohols to alkyl bromides using pyridinium based ionic liquids: A green alternative to appel reaction
Das, Pranab J.,Das, Jupitara,Das, Dimpee
, p. 651 - 654 (2018/02/09)
Pyridinium based ionic liquids namely 4-...
110-53-2 Process route
-
-
109-66-0,8031-35-4,9078-70-0
pentane
-
-
107-81-3
2-bromopentane
-
-
1809-10-5
3-bromopentane
-
-
110-53-2
1-Bromopentane
| Conditions | Yield |
|---|---|
|
With
Trichloroethylene; N-bromobis(trimethylsilyl)amine;
at 49.9 ℃;
for 1.58333h;
Product distribution;
Mechanism;
Irradiation;
variation of temperature, time, reagents;
|
|
|
With
bromine; sodium t-butanolate;
In
cyclohexane;
at 40 ℃;
Further Variations:;
Reagents;
Temperatures;
Product distribution;
|
-
-
628-17-1
amyl iodide
-
-
18243-41-9
(bromomethyl)trimethylsilane
-
-
110-53-2
1-Bromopentane
-
-
4206-67-1
iodo(trimethylsilyl)methane
| Conditions | Yield |
|---|---|
|
With
triisooctyl amine;
Equilibrium constant;
|
110-53-2 Upstream products
-
512-85-6
ascaridole
-
71-41-0
pentan-1-ol
-
628-80-8
1-methoxypentane
-
109-67-1
1-penten
110-53-2 Downstream products
-
54798-87-7
2-(1-Thiahexyl)-thiophen
-
66894-62-0
diethyl-oct-2-ynyl-amine
-
177715-63-8
4-pentyloxy-benzoic acid ethyl ester
-
13900-82-8
2-methyl-4-oxo-3-pentyl-cyclohex-2-enecarboxylic acid ethyl ester
Relevant Products
-
Cyclopentyl bromideCAS：137-43-9
-
1-Bromo-4-chlorobutaneCAS：6940-78-9
-
1-Bromo-3-methylbutaneCAS：107-82-4
