2113-57-7
- Product Name：3-Bromobiphenyl
- Molecular Formula：C12H9Br
- Purity：99%
- Molecular Weight：233.107
Product Details
pd_meltingpoint:9oC
Appearance:Colorless to pale yellow liquid
Purity:99%
Quality Manufacturer Supply High Purity 99% 3-Bromobiphenyl 2113-57-7 with Reasonable Price
- Molecular Formula:C12H9Br
- Molecular Weight:233.107
- Appearance/Colour:Colorless to pale yellow liquid
- Vapor Pressure:0.00205mmHg at 25°C
- Melting Point:9oC
- Refractive Index:1.637-1.641
- Boiling Point:300 °C at 760 mmHg
- Flash Point:135.6 °C
- PSA：0.00000
- Density:1.363 g/cm3
- LogP:4.11610
3-Bromobiphenyl(Cas 2113-57-7) Usage
|
synthesis |
Add 1-bromo-3-iodobenzene (4.67 g, 16.5mmol), phenylboronic acid (1.83 g, 15.0 mmol), Pd (OAc)2 (101 mg, 0.450 mmol), PPh3 (239 mg, 0.911 mmol), and K2CO3 (6.23 g, 45.1 mmol) to a 200 mL twonecked round-bottom flask. Add toluene (40 mL) and water (40 mL) via syringe and reflux the mixture (bath temp. 100°C) for 24 h. Extract the resulting mixture with ethyl acetate (30 mL x 3). Dry the combined organic layer over Na2SO4 and concentrate in vacuo. Purify the residue to silica gel column chromatography (eluent:hexane). |
|
Synthesis Reference(s) |
The Journal of Organic Chemistry, 41, p. 24, 1976 DOI: 10.1021/jo00863a005 |
|
Air & Water Reactions |
Insoluble in water. |
|
Reactivity Profile |
3-Bromobiphenyl may be sensitive to light. 3-Bromobiphenyl may react with oxidizing materials. |
|
Fire Hazard |
Flash point data for 3-Bromobiphenyl are not available. 3-Bromobiphenyl is probably combustible. |
|
General Description |
Clear yellow viscous liquid. Insoluble in water. |
InChI:InChI=1/C12H9Br/c13-12-8-4-7-11(9-12)10-5-2-1-3-6-10/h1-9H
2113-57-7 Relevant articles
-
Mowry et al.
, p. 1916 (1948)
-
-
Lichtin,Leftin
, p. 4207 (1952)
-
Synthesis and catalytic activity of nickel(II) complexes containing NCN pincer ligands
Nair, Ashwin G.,McBurney, Roy T.,Gatus, Mark R.D.,Walker, D.Barney,Bhadbhade, Mohan,Messerle, Barbara A.
, p. 63 - 70 (2017)
In this study, nickel(II) complexes [Lme...
-
de la Mare,Hassan
, p. 3004,3006 (1957)
-
The photochemistry of polyhaloarenes XIII. The photohydrodehalogenation of 3,4-dibromobiphenyl
Freeman, Peter K.,Jang, Jung-Suk,Haugen, Christian M.
, p. 8397 - 8406 (1996)
Irradiation of 3,4-dibromobiphenyl (BpBr...
-
Huber et al.
, p. 1109,1111 (1946)
-
Synthesis, Structure, and Chiroptical Properties of Indolo- and Pyridopyrrolo-Carbazole-Based C2-Symmetric Azahelicenes
Taniguchi, Taisei,Nishii, Yuji,Mori, Tadashi,Nakayama, Ken-ichi,Miura, Masahiro
supporting information, p. 7356 - 7361 (2021/04/26)
Treatment of 11,12-bis(1,1’-biphenyl-3-y...
Facile synthesis of NC(sp3)O pincer palladium complexes and their use as efficient catalysts for Suzuki-Miyaura reaction of aryl bromides in aqueous medium
Gong, Jun-Fang,Li, Nan,Pan, Ya-Ping,Song, Mao-Ping,Yang, Jing-Jing,Zhu, Zhi-Wu
, (2020/12/15)
Two NC(sp3)O pincer palladium(II) comple...
METHOD OF PRODUCING HALOGEN COMPOUND
-
Paragraph 0052-0060, (2021/05/07)
PROBLEM TO BE SOLVED: To provide a metho...
Palladium (II)–Salan Complexes as Catalysts for Suzuki–Miyaura C–C Cross-Coupling in Water and Air. Effect of the Various Bridging Units within the Diamine Moieties on the Catalytic Performance
Bunda, Szilvia,Joó, Ferenc,Kathó, ágnes,Udvardy, Antal,Voronova, Krisztina
supporting information, (2020/09/18)
Water-soluble salan ligands were synthes...
2113-57-7 Process route
-
-
591-50-4
iodobenzene
-
-
89598-96-9
(3-bromophenyl)boronic acid
-
-
16400-51-4
3,3'-dibromobiphenyl
-
-
2113-57-7
3-bromobiphenyl
| Conditions | Yield |
|---|---|
|
With
potassium phosphate;
[N,N,O]-tridentate unsymmetrical Schiff base Au(I);
In
o-xylene;
for 3h;
|
|
|
With
potassium phosphate; C44H44N3O2PdPolSi;
In
5,5-dimethyl-1,3-cyclohexadiene; water;
at 130 ℃;
for 3h;
solid phase reaction;
|
-
-
108-86-1,52753-63-6
bromobenzene
-
-
17420-03-0
N-sulphinylphenylhydrazine
-
-
2052-07-5
2-Bromobiphenyl
-
-
92-66-0
4-bromo-1,1'-biphenyl
-
-
2113-57-7
3-bromobiphenyl
-
-
882-33-7
diphenyldisulfane
| Conditions | Yield |
|---|---|
|
at 135 ℃;
for 72h;
Further byproducts given;
|
12.7% 6.9% 20.9% 1.1% |
|
at 135 ℃;
for 72h;
Further byproducts given;
|
19.5% 12.9% 1.1% 8.1% |
2113-57-7 Upstream products
-
110-86-1
pyridine
-
108-86-1
bromobenzene
-
94-36-0
dibenzoyl peroxide
-
938-81-8
N-nitrosoacetanilide
2113-57-7 Downstream products
-
71912-71-5
3-(2-hydroxy-1-ethyl)-1,1'-biphenyl
-
113792-74-8
3-phenyldiphenyl sulfide
-
3378-09-4
(biphenyl-3-yl)(phenyl)methanone
-
98586-20-0
di(1,1'-biphenyl-3-yl)methanol
Relevant Products
-
Cyclopentyl bromideCAS：137-43-9
-
PTris(dibenzylideneacetone)dipalladiumCAS：51364-51-3
-
1,6-DibromohexaneCAS：629-03-8
