20440-95-3

  • Product Name:4,4'-Dimethyltriphenylamine
  • Molecular Formula:C20H19N
  • Purity:99%
  • Molecular Weight:273.378
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Product Details

pd_meltingpoint:112 °C

Appearance:White Powder

Purity:99%

Chinese Manufacturer Supply 4,4'-Dimethyltriphenylamine 20440-95-3 On Stock with Competitive Price

  • Molecular Formula:C20H19N
  • Molecular Weight:273.378
  • Appearance/Colour:White Powder 
  • Vapor Pressure:3.52E-07mmHg at 25°C 
  • Melting Point:112 °C 
  • Refractive Index:1.627 
  • Boiling Point:417.5 °C at 760 mmHg 
  • PKA:-2.19±0.50(Predicted) 
  • Flash Point:183.5 °C 
  • PSA:3.24000 
  • Density:1.079 g/cm3 
  • LogP:5.77320 

4,4'-Dimethyltriphenylamine(Cas 20440-95-3) Usage

Purification Methods

Crystallise the amine once from EtOAc, then twice from EtOH to give pale yellow needles [Marsden J Chem Soc 627 1937, Beilstein 12 III 2033.]

InChI:InChI=1/C20H19N/c1-16-8-12-19(13-9-16)21(18-6-4-3-5-7-18)20-14-10-17(2)11-15-20/h3-15H,1-2H3

20440-95-3 Relevant articles

Copper(I)-anilide complex [Na(phen)3][Cu(NPh2) 2]: An intermediate in the copper-catalyzed N-Arylation of N-Phenylaniline

Tseng, Chia-Kai,Lee, Chi-Rung,Han, Chien-Chung,Shyu, Shin-Guang

, p. 2716 - 2723 (2011)

Complex [Na(phen)3][Cu(NPh2)2] (2), cont...

Amination and amidation of aryl iodides catalyzed by copper(I)- phenanthroline complexes

Moriwaki, Kazuyuki,Satoh, Kazuyoshi,Takada, Masahiro,Ishino, Yoshio,Ohno, Toshinobu

, p. 7559 - 7562 (2005)

Four kinds of copper(I)-phenanthroline c...

Heterogeneously Catalyzed Selective Decarbonylation of Aldehydes by CeO2-Supported Highly Dispersed Non-Electron-Rich Ni(0) Nanospecies

Matsuyama, Takehiro,Yatabe, Takafumi,Yabe, Tomohiro,Yamaguchi, Kazuya

, p. 13745 - 13751 (2021/11/17)

Aldehyde decarbonylation has been extens...

Design and synthesis of efficient electrogenerated chemiluminescent emitters derived from pyrene

Cappellari, Maria V.,Mangione, María I.,Spanevello, Rolando A.,Marzari, Gabriela,Morales, Gustavo M.,Fungo, Fernando

, p. G163 - G170 (2019/05/21)

The design and synthesis of novel dendri...

Donor and acceptor substituted triphenylamines exhibiting bipolar charge-transporting and NLO properties

Gudeika, Dalius,Bundulis, Arturs,Mihailovs, Igors,Volyniuk, Dmytro,Rutkis, Martins,Grazulevicius, Juozas V.

, p. 431 - 440 (2017/02/10)

Donor-acceptor type triphenylamine-based...

PdCl2(Ph3P)2/Salicylaldimine Catalyzed Diarylation of Anilines with Unactivated Aryl Chlorides

Tao, Xiaochun,Li, Lei,Zhou, Yu,Qian, Xuanying,Zhao, Min,Cai, Liangzhen,Xie, Xiaomin

supporting information, p. 1749 - 1754 (2017/10/06)

Triphenylphosphine and salicylaldimine c...

20440-95-3 Process route

bromobenzene
108-86-1,52753-63-6

bromobenzene

di-p-tolylamine
620-93-9

di-p-tolylamine

N-phenyl-di-p-tolylamine
20440-95-3

N-phenyl-di-p-tolylamine

Conditions
Conditions Yield
di-p-tolylamine; With ethylmagnesium bromide; In diethyl ether; at 0 - 40 ℃; for 2h; Inert atmosphere;
bromobenzene; With lithium bromide; iron(II) chloride; In 5,5-dimethyl-1,3-cyclohexadiene; at 140 ℃; for 72h; Inert atmosphere;
96%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In o-xylene; at 120 ℃; for 20h; Inert atmosphere;
96%
With chloro(1-naphthyl)bis(triphenylphosphine)nickel(II); sodium hydride; triphenylphosphine; In toluene; white oil; at 120 ℃; for 12h; Inert atmosphere;
85%
With bis(triphenylphosphine)nickel(II) chloride; ethylmagnesium bromide; triphenylphosphine; In tetrahydrofuran; at 90 ℃; for 5h;
76%
4-[N,N-di(p-tolyl)amino]benzaldehyde
42906-19-4

4-[N,N-di(p-tolyl)amino]benzaldehyde

N-phenyl-di-p-tolylamine
20440-95-3

N-phenyl-di-p-tolylamine

Conditions
Conditions Yield
With 1.26 wt% Ni(0) nanospecies supported on CeO2; In toluene; at 150 ℃; under 760.051 Torr; Inert atmosphere;
98%

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