624-31-7
- Product Name：1-Iodo-4-methylbenzene
- Molecular Formula：C7H7I
- Purity：99%
- Molecular Weight：218.037
Product Details
pd_meltingpoint:33-36 °C
Appearance:white to light yellow crystalline low melting mass
Purity:99%
Manufacturer Supply Best Quality 1-Iodo-4-methylbenzene 624-31-7 with Efficient Transportation
- Molecular Formula:C7H7I
- Molecular Weight:218.037
- Appearance/Colour:white to light yellow crystalline low melting mass
- Vapor Pressure:0.264mmHg at 25°C
- Melting Point:33-36 °C
- Refractive Index:1.604
- Boiling Point:211.5 °C at 760 mmHg
- Flash Point:86.3 °C
- PSA：0.00000
- Density:1.706 g/cm3
- LogP:2.59960
4-Iodotoluene(Cas 624-31-7) Usage
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Synthesis Reference(s) |
The Journal of Organic Chemistry, 52, p. 691, 1987 DOI: 10.1021/jo00380a041Synthesis, p. 572, 1980 DOI: 10.1055/s-1980-29128 |
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Purification Methods |
Crystallise 4-iodotoluene from EtOH and.or distil it. [Beilstein 5 IV 840.] |
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General Description |
4-Iodotoluene undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium. Cobalt-catalyzed coupling of 4-iodotoluene with thiophenols and alkanethiols has been investigated. Palladium/copper-catalyzed Sonogashira cross-coupling reaction of 4-iodotoluene with phenylacetylene has been studied. |
InChI:InChI=1/C7H7I/c1-6-2-4-7(8)5-3-6/h2-5H,1H3
624-31-7 Relevant articles
Palladium-Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand-Assisted Halide Exchange
Boehm, Philip,Cacherat, Bastien,Lee, Yong Ho,Martini, Tristano,Morandi, Bill
supporting information, p. 17211 - 17217 (2021/07/02)
We report an efficient and broadly appli...
Synthesis of biaryl compounds via Suzuki homocoupling reactions catalyzed by metal organic frameworks encapsulated with palladium nanoparticles
Bao, Yan-Sai,Cui, Xin-Yu,Han, Zheng-Bo,Li, Xin,Tang, Hong,Yang, Ming,Zhang, Yu-Yang,Zhao, Kun,Zhou, Mei-Li
, (2020/12/17)
Heterogeneous homocoupling reactions of ...
The graphite-catalyzed: ipso -functionalization of arylboronic acids in an aqueous medium: metal-free access to phenols, anilines, nitroarenes, and haloarenes
Badgoti, Ranveer Singh,Dandia, Anshu,Parewa, Vijay,Rathore, Kuldeep S.,Saini, Pratibha,Sharma, Ruchi
, p. 18040 - 18049 (2021/05/29)
An efficient, metal-free, and sustainabl...
Metal-Organic Framework-Confined Single-Site Base-Metal Catalyst for Chemoselective Hydrodeoxygenation of Carbonyls and Alcohols
Antil, Neha,Kumar, Ajay,Akhtar, Naved,Newar, Rajashree,Begum, Wahida,Manna, Kuntal
supporting information, p. 9029 - 9039 (2021/06/28)
Chemoselective deoxygenation of carbonyl...
624-31-7 Process route
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C15H15N3O
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13329-40-3
4-Iodoacetophenone
-
-
624-31-7
4-tolyl iodide
| Conditions | Yield |
|---|---|
|
With
boron trifluoride diethyl etherate; sodium iodide;
In
acetonitrile;
at 40 ℃;
for 2h;
|
-
-
696-62-8
para-iodoanisole
-
-
874-60-2
4-methyl-benzoyl chloride
-
-
624-31-7
4-tolyl iodide
-
-
100-07-2
4-methoxy-benzoyl chloride
| Conditions | Yield |
|---|---|
|
With
(Xantphos)Pd(4-C6H4NO2)(I);
In
benzene;
at 90 ℃;
for 20h;
Equilibrium constant;
Sealed tube;
Inert atmosphere;
|
624-31-7 Upstream products
-
57573-52-1
4-methylbenzene diazonium
-
60-29-7
diethyl ether
-
16825-72-2
4-iodoxy-toluene
-
925-90-6
ethylmagnesium bromide
624-31-7 Downstream products
-
16825-72-2
4-iodoxy-toluene
-
342043-69-0
2-(phenyl(p-tolyl)amino)benzoic acid
-
104-85-8
para-methylbenzonitrile
-
106-44-5
p-cresol
Relevant Products
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Methyl 2-iodobenzoateCAS：610-97-9
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4,4'-Oxydiphthalic anhydrideCAS：1823-59-2
-
2,2-Bis[4-(3,4-dicarboxyphenoxy)phenyl]propanedianhydrideCAS：38103-06-9
