76185-65-4

  • Product Name:N,N,N',N'-Tetrakis(4-methylphenyl)-benzidine
  • Molecular Formula:C40H36 N2
  • Purity:99%
  • Molecular Weight:544.739
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Product Details

pd_meltingpoint:218 °C

Purity:99%

Factory sells N,N,N',N'-Tetrakis(4-methylphenyl)-benzidine 76185-65-4 with sufficient production capacity

  • Molecular Formula:C40H36 N2
  • Molecular Weight:544.739
  • Melting Point:218 °C 
  • Boiling Point:701.741 °C at 760 mmHg 
  • PKA:-1.70±0.60(Predicted) 
  • Flash Point:310.749 °C 
  • PSA:6.48000 
  • Density:1.13 g/cm3 
  • LogP:11.52680 

76185-65-4 Relevant articles

The molecular structures and electrochemical response of "twisted" tetra(aryl)benzidenes

Low, Paul J.,Paterson, Michael A. J.,Goeta, Andres E.,Yufit, Dmitry S.,Howard, Judith A. K.,Cherryman, Julian C.,Tackley, Daniel R.,Brown, Bev

, p. 2516 - 2523 (2004)

The compounds N,N,N′,N′-tetra(4-methylph...

Catalytic and Aerobic Oxidative Biaryl Coupling of Anilines Using a Recyclable Heterogeneous Catalyst for Synthesis of Benzidines and Bicarbazoles

Matsumoto, Kenji,Toubaru, Yasunori,Tachikawa, Shohei,Miki, Ayaka,Sakai, Kentaro,Koroki, Syota,Hirokane, Tsukasa,Shindo, Mitsuru,Yoshida, Masahiro

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In this study, a heterogeneous rhodium-c...

PdCl2(Ph3P)2/Salicylaldimine Catalyzed Diarylation of Anilines with Unactivated Aryl Chlorides

Tao, Xiaochun,Li, Lei,Zhou, Yu,Qian, Xuanying,Zhao, Min,Cai, Liangzhen,Xie, Xiaomin

, p. 1749 - 1754 (2017/10/06)

Triphenylphosphine and salicylaldimine c...

Metal-Free Oxidative C-C Coupling of Arylamines Using a Quinone-Based Organic Oxidant

Maddala, Sudhakar,Mallick, Sudesh,Venkatakrishnan, Parthasarathy

, p. 8958 - 8972 (2017/09/11)

A variety of arylamines are shown to und...

Method of manufacturing hydroxytriarylamine compd.

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Paragraph 0069-0072; 0073; 0085-0086, (2018/03/13)

PROBLEM TO BE SOLVED: To provide a metho...

76185-65-4 Process route

4-(4-bromophenyl)bromobenzene
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4-(4-bromophenyl)bromobenzene

di-p-tolylamine
620-93-9

di-p-tolylamine

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl
76185-65-4

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl

Conditions
Conditions Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydroxide; In o-xylene; at 200 ℃; for 2h; Solvent; Temperature; Inert atmosphere; Dean-Stark;
96.2%
With sodium tert-pentoxide; palladium diacetate; 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantane; In toluene; at 20 - 90 ℃; for 1.58333 - 1.83333h;
95.1%
4-bromo-N,N-di-p-tolylaniline
58047-42-0

4-bromo-N,N-di-p-tolylaniline

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl
76185-65-4

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl

Conditions
Conditions Yield
With manganese; [2,2]bipyridinyl; 1,5-cis,cis-cyclooctadiene; nickel dibromide; In N,N-dimethyl-formamide; toluene; at 20 ℃;
4-bromo-N,N-di-p-tolylaniline; In N,N-dimethyl-formamide; toluene; at 50 ℃; for 48h;
90%

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